




InChI:InChI=1/C19H26O/c1-18-9-3-4-16(18)15-6-5-13-12-14(20)7-11-19(13,2)17(15)8-10-18/h3,9,12,15-17H,4-8,10-11H2,1-2H3
We report here a mechanistically distinc...
Cu-catalyzed Pd-free Sonogashira couplin...
Ullmann-type C-N coupling of vinyliodide...
Flash vacuum pyrolysis (FVP) or thermoly...
17β-methoxycarbonyloxy-androst-4-en-3-one
4,16-androstadien-3-one
| Conditions | Yield |
|---|---|
|
In
toluene;
at 460 ℃;
|
90% |
|
In
acetone; toluene;
|
90% |
17β-tosyloxyandrostan-4-en-3-one
4,16-androstadien-3-one
| Conditions | Yield |
|---|---|
|
17β-tosyloxyandrostan-4-en-3-one;
With
tetrabutylammonium acetate;
In
1-methyl-pyrrolidin-2-one;
at 160 ℃;
for 4h;
With
potassium hydroxide;
In
ethanol;
at 20 ℃;
for 48h;
|
61% |
|
With
aluminum oxide;
In
benzene;
for 20h;
Heating;
|
3-oxoandrost-4-en-17α-yl benzoate
HAD
testosterone
17β-methoxycarbonyloxy-androst-4-en-3-one
Androstene oxide
4-androsten-3-one
5α-androstan-5-ol